Spectral Splitting as a Route to Promote Total Efficiency of Hybrid Photovoltaic Thermal with a Halide Perovskite Cell

Abstract

Integrating photovoltaic (PV) perovskite solar cells and photothermal (PT) collectors into a hybrid photovoltaic thermal (PVT) is a promising method to further improve the conversion efficiency of solar energy via salvaging the near‐infrared energy. Herein, a 1D photonic crystal of Si/GeO2 to construct a spectrally selective PV–PT splitter that selectively reflects solar energy in the PV band while absorbing the rest is utilized. The fabricated PV–PT splitter reveals a considerable reflectance of 92.3% in the PV band, a comprehensive absorptance of 52.1% in the PT band, as well as good angular independence over a wide incident range of 0–70°. The hybrid PVT design with the Si/GeO2 spectral splitter/absorber and a perovskite solar cell (PSC) acquires a solar‐to‐electrical efficiency of 29.3% higher than the single PSC (24.6%). In addition, the temperature of PSCs in the hybrid PVT design under 1 kW m−2 solar irradiation can be significantly reduced by 15 °C owing to suppression of ineffectively converted incident photons on the PV cells. This appealing strategy highlights a new avenue for further enhancing the total electrical efficiency via broadening the utilization of the entire solar spectrum in the hybrid PVT design integrated with wide‐bandgap perovskite solar cells.