Quantum Composites with Charge‐Density‐Wave Fillers

Author:

Barani Zahra1ORCID,Geremew Tekwam1ORCID,Stokey Megan2ORCID,Sesing Nicholas3ORCID,Taheri Maedeh1ORCID,Hilfiker Matthew J.2ORCID,Kargar Fariborz1ORCID,Schubert Mathias2ORCID,Salguero Tina T.3ORCID,Balandin Alexander A.1ORCID

Affiliation:

1. Phonon Optimized Engineered Materials Center Department of Electrical and Computer Engineering University of California, Riverside Riverside CA 92521 USA

2. Department of Electrical and Computer Engineering University of Nebraska Lincoln NE 68588 USA

3. Department of Chemistry University of Georgia Athens GA 30602 USA

Abstract

AbstractA unique class of advanced materials—quantum composites based on polymers with fillers composed of a van der Waals quantum material that reveals multiple charge‐density‐wave quantum condensate phases—is demonstrated. Materials that exhibit quantum phenomena are typically crystalline, pure, and have few defects because disorder destroys the coherence of the electrons and phonons, leading to collapse of the quantum states. The macroscopic charge‐density‐wave phases of filler particles after multiple composite processing steps are successfully preserved in this work. The prepared composites display strong charge‐density‐wave phenomena even above room temperature. The dielectric constant experiences more than two orders of magnitude enhancement while the material maintains its electrically insulating properties, opening a venue for advanced applications in energy storage and electronics. The results present a conceptually different approach for engineering the properties of materials, extending the application domain for van der Waals materials.

Funder

Office of the Secretary of Defense

Office of Naval Research

U.S. Department of Energy

Basic Energy Sciences

National Science Foundation

Publisher

Wiley

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

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