Carbon‐negative syngas production: A comprehensive assessment of biomass pyrolysis coupling chemical looping reforming

Author:

Liu Gen1,Zhang Rongjiang1,Sun Zhongshun1,Zhang Bo1,Wang Zhichao1,Liu Jingjun1,Yang Bolun1ORCID,Wu Zhiqiang1ORCID

Affiliation:

1. Shaanxi Key Laboratory of Energy Chemical Process Intensification, School of Chemical Engineering and Technology Xi'an Jiaotong University Xi'an Shaanxi China

Abstract

AbstractThis article introduces a pyrolysis chemical looping reforming (PCLR) process that produces carbon‐negative syngas in autothermal operation. To enhance the system's carbon negativity, a process configuration with oxygen carrier two‐stage regeneration is adopted, enabling internal CO2 utilization. The PCLR process is systematically evaluated and compared to chemical looping gasification and steam gasification processes in the process performance, energy efficiency, and environmental impact using a process model. Results reveal significant improvements over chemical looping gasification, including 69%, 45%, and 4% improvement in syngas yield, energy efficiency, and environmental benefit. Process analysis demonstrates that decoupling volatile reforming from pyrolysis and combustion enhances syngas quality, energy efficiency, and process flexibility. While the two‐stage regeneration sacrifices syngas production, it contributes to a 4% increase in carbon negativity and a 15% reduction in carbon emissions. Thus, the PCLR process effectively overcomes the limitations of chemical looping gasification systems and exhibits excellent process intensification performance.

Funder

K. C. Wong Education Foundation

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemical Engineering,Environmental Engineering,Biotechnology

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3