Affiliation:
1. School of Material and Energy Guangdong University of Technology Guangzhou China
2. Guangdong Provincial Key Laboratory of Functional Soft Matter Guangzhou China
3. School of Petrochemical Technology Lanzhou University of Technology Lanzhou China
Abstract
AbstractThe use of double emulsions (DEs), which represent colloidal structures composed of droplets nested within droplets, can provide for unparallel droplet manipulation in droplet‐based microfluidic technology due to their unique core–shell structures. The controlled release of cores in DEs is of particular interest. However, this process remains poorly explored. In this work, the thermocapillary flow induced by a temperature gradient is used as a driving force to control the core release and the impacts of different linear temperature gradients, core diameters, shell diameter, and core/shell diameter ratios on the thermocapillary flow and core release characteristics of DE droplets consisting of a water‐in‐n‐hexadecane‐in‐water system within a cylindrical microchannel are investigated. Most of the core and shell diameter conditions considered result in a double‐core release process, where the inner droplet volume is partially ejected before the remaining core is rewrapped by the outer droplet, and the remaining inner droplet volume is ejected later during a second core release event. However, relatively small core diameters of 50 and 75 μm produce conditions where the full inner droplet volume is ejected during a single‐core release process. In addition, we provide empirical relationships for accurately determining the time at which core release initially occurs under given DE parameters as well as for precisely determining whether the applied conditions will lead to single‐ or double‐core release processes. Therefore, the results of this study provide insights enabling the development of accurate inner droplet release technologies under thermocapillary migration.
Funder
National Natural Science Foundation of China
Cited by
3 articles.
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