Copper promoted, directed sulfenylation and phenoxylation of benzamide C−H bonds-Reference-Cited by-同舟云学术

Copper promoted, directed sulfenylation and phenoxylation of benzamide C−H bonds

Published:2023-03-17 Issue:2 Volume:61 Page:204-209
ISSN:2572-8288
Container-title:Vietnam Journal of Chemistry
language:en
Short-container-title:Vietnam Journal of Chemistry

Author:

Ha Nguyen Van Vinh¹²,Ha Nguyen Thi Thu¹²^ORCID,Khanh Ong Ngoc¹²,Phuong Dinh Truc¹²,Nhat Ho Thanh¹²,Tung Nguyen Thanh¹²

Affiliation:

1. Faculty of Chemical Engineering Ho Chi Minh City University of Technology (HCMUT) 268 Ly Thuong Kiet Street, District 10 Ho Chi Minh City 70000 Viet Nam

2. Vietnam National University Ho Chi Minh City Linh Trung Ward, Thu Duc City Ho Chi Minh City 70000 Viet Nam

Abstract

AbstractHerein we reported a method for copper pivalate mediated, directed functionalization of ortho C−H bonds in (2‐methylthio)aniline benzamides. Diaryl disulfides were used for thiolation, while successful phenoxylation was obtained with phenol as the coupling agent. Our report marks a rare example for flexible transformation of benzamide C(sp2)−H bonds into the corresponding unsymmetrical diaryl ethers and thioethers.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/vjch.202200119

Reference18 articles.

1. Palladium-Catalyzed Transformations of Alkyl C–H Bonds

2. 3d Transition Metals for C–H Activation

3. Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

4. Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

5. Highly Regioselective Arylation of sp3 C−H Bonds Catalyzed by Palladium Acetate

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