Preparation and corrosion protection of polypyrrole/SiO2 nanocomposite doped with 3‐nitrosalicylic acid on aluminum

Author:

Van Khoe Le1,Hung Ha Manh2,Thuy Hoang Thi3,Binh Pham Huy4,Anh Bui Tuan3,Duc Le Minh5,Huong Nguyen Thi6,Oanh Doan Thi Yen7,Thai Nguyen Xuan8,Trung Vu Quoc3ORCID

Affiliation:

1. Hong Duc University Thanh Hoa City Vietnam

2. Faculty of General Education Hanoi University of Mining and Geology Hanoi Vietnam

3. Faculty of Chemistry Hanoi National University of Education Hanoi Vietnam

4. Hanoi–Amsterdam High School for the Gifted Hanoi Vietnam

5. Branch of National Institute of Occupational Safety and Health and Environmental Protection in Central of Vietnam Da Nang Vietnam

6. Faculty of Chemistry University of Science and Education The University of Da Nang Da Nang Vietnam

7. Publishing House for Science and Technology Vietnam Academy of Science and Technology Hanoi Vietnam

8. Institute for Tropical Technology Vietnam Academy of Science and Technology Hanoi Vietnam

Abstract

AbstractPolypyrrole/SiO2 nanocomposite doped with 3‐nitrosalicylic acid was synthesized in three concentrations of 3‐nitrosalicylic acid: 0.01 m, 0.005 m, and 0.0025 m. FTIR spectroscopy, thermogravimetric analysis (TGA), Raman scattering spectroscopy, and FESEM imaging further assisted in determining the shape and structure of the polypyrrole/nanocomposite product. The aluminum protection arrangement of the paint film comprising polypyrrole/SiO2 nanocomposite doped with 3‐nitrosalicylic acid was proven by electrochemical methods. The salt spray test results also demonstrated the protective efficacy of the paint film comprising polypyrrole/SiO2 nanocomposite doped with 3‐nitrosalicylic acid to suppress corrosion. The best corrosion prevention results were obtained with a polypyrrole/SiO2 nanocomposite dispersion paint film doped with 0.01 m 3‐nitrosalicylic acid at a concentration of 2%.

Publisher

Wiley

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