Synthesis and Application of a Perfluorinated Ammoniumyl Radical Cation as a Very Strong Deelectronator-Reference-Cited by-同舟云学术

Synthesis and Application of a Perfluorinated Ammoniumyl Radical Cation as a Very Strong Deelectronator

Published:2020-04-24 Issue:24 Volume:59 Page:9453-9459
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew. Chem. Int. Ed.

Author:

Schorpp Marcel¹^ORCID,Heizmann Tim¹,Schmucker Maximillian¹,Rein Stephan²,Weber Stefan²^ORCID,Krossing Ingo¹^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum (FMF)Albert-Ludwigs-Universität Freiburg Albertstrasse 21 79104 Freiburg Germany

2. Institut für Physikalische ChemieAlbert-Ludwigs-Universität Freiburg Albertstrasse 21 79104 Freiburg Germany

Funder

Carl-Zeiss-Stiftung

Deutsche Forschungsgemeinschaft

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202002768

Reference70 articles.

2. Here and in the following we use the particle-based view on the classical oxidation=deelectronation and reduction=electronation processes. Thus an oxidant is a deelectronator and a reductant an electronator. This evolved from our work on the protoelectric potential map (PPM) for keeping with the successful and self-explaining acid–base picture. Thus the equivalent to a deprotonation reaction is a deelectronation reaction. This is in keeping with earlier textbook suggestions by Bockris and Reddy and follows our concept paper on the PPM (Ref. [1 b]) and the recent Review (Ref. [1 c]);

3. The Protoelectric Potential Map (PPM): An Absolute Two-Dimensional Chemical Potential Scale for a Global Understanding of Chemistry

4. Basic Remarks on Acidity

5. Grundlegende Bemerkungen zur Azidität

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