Affiliation:
1. Bioproducts Discovery and Development Centre, Department of Plant Agriculture, Crop Science Building University of Guelph Guelph Ontario Canada
2. School of Engineering, Thornbrough Building University of Guelph Guelph Ontario Canada
Abstract
AbstractThis research focuses on the melt processing of biocomposites from a biodegradable polymer blend mixed with hybrid fillers through injection molding technique. An optimized blend ratio (60/40 wt%) poly(butylene succinate‐co‐butylene adipate) (PBSA) and poly(butylene adipate‐co‐terephthalate) (PBAT) demonstrated promising results after blending with a mixture of walnut shell powder (WSP), corn starch and talc in various proportions for use in rigid packaging. The addition of hybrid fillers (i) 10% WSP with 15% talc and (ii) 5% WSP with 5% starch and 15% talc to the polymer blend (60%PBSA/40%PBAT) improved tensile modulus (160% and 162%, respectively) and flexural modulus (147% and 153%, respectively) because of the dispersion of stiffer talc and WSP. Following the addition of fillers, tensile strength of the composites decreased. However, flexural strength improved significantly after filler introduction because of better stress transfer ability. Rheological analysis of filled composites with starch or WSP (25%) depicted similar characteristics of the polymer blend, indicating lower viscosity than hybrid composites. The abundant hydroxyl groups in starch explained the increased water absorption and decreased contact angle compared with other composites. This research's novelty encompasses utilizing low‐cost biomasses with mineral filler into an under‐researched biodegradable polymer blend suitable for single‐use rigid packaging applications.
Funder
Natural Sciences and Engineering Research Council of Canada