The Use of the Mannich Reaction toward Amino‐Based Anthraquinone Applied in Aqueous Redox Flow Battery

Author:

Almeida Renata G.1ORCID,De Silva Oshadie2,Delolo Fábio G.1ORCID,Araujo Maria H.1ORCID,Maniam Subashani2ORCID,da Silva Júnior Eufrânio N.1ORCID

Affiliation:

1. Instituto de Ciências Exatas, Departamento de Química Universidade Federal de Minas Gerais Belo Horizonte MG 31270‐901 Brazil

2. Applied Chemistry and Environmental Science, School of Sciences STEM College RMIT University Melbourne VIC 3001 Australia

Abstract

A water‐soluble anthraquinone derived from alizarin, 3HAAQ, is introduced as the redox‐active material in a negative potential electrolyte (anolyte) for aqueous redox flow batteries operating at pH 14. The synthesis of 3HAAQ is carried out using the Mannich reaction, which significantly improves the solubility of the new compound, an important factor for its use in RFB. Pairing with potassium ferri/ferrocyanide positive electrolyte, this flow battery exhibits an open‐circuit voltage of 1.24 V and maintains nearly 80% of the theoretical capacity at 40 mA cm−2 current density.

Funder

Royal Society of Chemistry

Publisher

Wiley

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