Detection of Ag+ by Synthesizing Fluorescent Copper Nanoparticles through Ultrasensitive Free Label Approach

Author:

Arthy M.1ORCID,Brindha J.2,Viswanathan Sabareeshwari3,Gnanasekar A. K.4ORCID,Nanammal V.5ORCID,Raju Raja6ORCID,Al Obaid Sami7,Almoallim Hesham S.8,Selva A.9

Affiliation:

1. Department of Energy and Environmental Engineering, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Chennai, 602105 Tamil Nadu, India

2. Department of Electronics and Instrumentation Engineering, Panimalar Engineering College, Chennai 600123, India

3. Department of Soil Science and Agricultural Chemistry, Amrita School of Agricultural Sciences, Amrita Vishwa Vidyapeetham University, Coimbatore, 642109 Tamil Nadu, India

4. Department of Electronics and Communication Engineering, Rajalakshmi Institute of Technology, Chennai 600124, India

5. Department of Electronics and Communication Engineering, Jeppiaar Engineering College, Chennai, India

6. Department of Mechanical Engineering, St. Joseph College of Engineering and Technology, St. Joseph University in Tanzania, Tanzania

7. Department of Botany and Microbiology, College of Science, King Saud University, PO Box -2455, Riyadh -11451, Saudi Arabia

8. Department of Oral and Maxillofacial Surgery, College of Dentistry, King Saud University, PO Box-60169, Riyadh -11545, Saudi Arabia

9. Department of Food Science, Sejong University, Republic of Korea

Abstract

Ag is abundant in nature and is employed in practically every aspect of life. Furthermore, Ag+ contamination poses a severe hazard to human and environmental health due to the extensive usage of Ag products. Traditional Ag+ detection techniques include drawbacks such as high operational costs, sophisticated operating units and instruments, and strong technical demands. The use of fluorescence copper nanoparticles in pollution detection has received a lot of attention in recent times. The development of copper nanoparticles and the detecting of Ag+ are the major topics of this research. Utilizing fluorescence copper nanoparticles produced utilizing glucose (Glc) as a reduction mediator like a fluorescent probe, and a simple approach for determining Ag+ in water was devised. Due to its appealing properties, including such dissolution rate, widespread availability, simplicity of synthesis process, and excellent biocompatibility, fluorescence copper nanoparticles (F-CuNPs) have sparked a lot of interest, and a lot of time and effort has gone into their synthesis and usage. The slightly elevated metallophilic Ag+ contact served as such sensing element, efficiently quenching the fluorescent of AuAg NCs. Moreover, these fluorescence nanoprobes could have been used to identify Ag+ in the atmosphere, implying that they might be used as practical, dual-functional, fast-responding, and label-free fluorescent sensors for health and environmental assessment. The experiment’s analytical methodology would be that silver ions could fast and efficiently extinguish the fluorescent of Glucose-CuNPs. In the Ag+ region at 100 mol/L–600 mol/L ( R = 0 9845 ), a strong linear relation was discovered; the color is progressively improved below the observable region and visually colorimetrical measurement. Furthermore, the Glucose-CuNP instrument only detected Ag+ and was unaffected by other metal ions, demonstrating that Glucose-CuNPs have strong sensitivity for Ag+ sensing. Glucose-CuNP, as a result, accomplishes the identification of substantial metal Ag+ ions, and it has promising future applicability in environmental monitoring.

Funder

Saveetha Institute of Medical and Technical Sciences

Publisher

Hindawi Limited

Subject

General Materials Science

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