The Vibrational-Translational Relaxation of CF2HCl in Argon

Author:

Tosa V.12,Bruzzese R.1,de Lisio C.1,Tescione D.1

Affiliation:

1. Dipartimento di Scienze Fisiche, Universita' di Napoli “Federico II”, Pad. 20, Mostra d'Oltremare, Napoli 80125, Italy

2. Institute for Isotopic and Molecular Technology, Cluj-Napoca, Romania

Abstract

We report in this paper results concerning the vibrational-translational (VT) rates of CF2HCl diluted in Ar as a neutral buffer. The dependence on the buffer concentration and on the initial vibrational energy distribution are obtained by using the 9R(48) and the 9R(34) CO2 laser lines for the excitation process. The differences observed between the results corresponding to the two lines bear valuable information about the dependence of the VT relaxation process on the specific initial conditions of vibrational excitation.

Publisher

Hindawi Limited

Subject

Spectroscopy,Biochemistry,Atomic and Molecular Physics, and Optics

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