Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2)-Reference-Cited by-同舟云学术

Synthesis, Crystal Structure Refinement, and Electrical Conductivity of Pb(8−x)Na2Smx(VO4)6O(x/2)

Published:2014 Issue: Volume:2014 Page:1-7
ISSN:2090-9063
Container-title:Journal of Chemistry
language:en
Short-container-title:Journal of Chemistry

Author:

Savankova Tatiana M.¹,Akselrud Lev G.²,Ardanova Lyudmyla I.³,Ignatov Alexey V.¹,Get’man Eugeni I.¹,Gladyshevskii Roman E.²,Loboda Stanislav N.¹

Affiliation:

1. Department of Inorganic Chemistry, Donetsk National University, 24 Universitetskaya, Donetsk 83001, Ukraine

2. Department of Inorganic Chemistry, Ivan Franko National University of Lviv, 6 Kyryla i Mephodiya Street, Lviv 79005, Ukraine

3. Department of Chemistry and Geology, Minnesota State University, 241 Ford Hall, Mankato, MN 56001, USA

Abstract

Solid solutions of Pb(8−x)Na2Smx(VO4)6O(x/2)were studied using X-ray diffraction analysis including Rietveld refinement and scanning electron microscopy and by measuring their electrical conductivity. Crystal structure of the solid solutions was refined and the solubility region0≤x≤0.2was determined for samarium substitution for lead under the scheme2Pb2++□→2Sm3++O2-. The influence of degree of substitution on the electrical conductivity of solid solutions was established.

Publisher

Hindawi Limited

Subject

General Chemistry

Link

http://downloads.hindawi.com/journals/jchem/2014/263548.pdf

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