Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides-Reference-Cited by-同舟云学术

Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides

Published:2017 Issue: Volume:2017 Page:1-9
ISSN:1687-8434
Container-title:Advances in Materials Science and Engineering
language:en
Short-container-title:Advances in Materials Science and Engineering

Author:

Babanly Dunya Mahammad¹^ORCID,Huseynov Qorkhmaz Mansur²,Aliev Ziya Saxaveddin³,Tagiyev Dilgam Babir¹,Babanly Mahammad Baba¹

Affiliation:

1. Institute of Catalysis and Inorganic Chemistry, ANAS, 1143 Baku, Azerbaijan

2. ANAS, Nakhchivan Branch, 7000 Nakhchivan, Azerbaijan

3. Azerbaijani State Oil and Industrial University, Azadlıg Av. 16/21, 1010 Baku, Azerbaijan

Abstract

The solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode. The EMF results were used to calculate the relative partial thermodynamic functions of thallium in alloys and the standard integral thermodynamic functions (-ΔfG0, -ΔfH0, and S0298) of Tl6SBr4 compound. All data regarding thermodynamic properties of thallium chalcogen-halides are generalized and comparatively analyzed. Consequently, certain regularities between thermodynamic functions of thallium chalcogen-halides and their binary constituents as well as degree of ionization (DI) of chemical bonding were revealed.

Publisher

Hindawi Limited

Subject

General Engineering,General Materials Science

Link

http://downloads.hindawi.com/journals/amse/2017/5370289.pdf

Reference22 articles.

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4. Thallium Chalcohalides for X-ray and γ-ray Detection

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