Recent Advances in Synthesis and Reactions of β-Amino-α ,β -Enones (Enaminones)

Author:

Farghaly Thoraya1,Abo Alnaja Alaa M.2,Shaaban Mohamed R.1

Affiliation:

1. Department of Chemistry, Faculty of Science, Cairo University, Giza 12613, Egypt

2. Department of Chemistry, Faculty of Applied Science, Umm Al-Qura University, Makkah Almukaramah, Saudi Arabia

Abstract

β-Amino-α,β-enones or β-enamino carbonyl compounds are versatile synthons intermediates for the construction of various bio-active heterocyclic compounds and have been established as multipurpose synthetic precursors in organic syntheses and in pharmaceutical developments. In this work, we will discuss the different synthetic routes to obtain β−amino−α,β-enones or β-enamino carbonyl compounds, their reactions, and their utility in the construction of organic frameworks and heterocyclic ring systems. Structurally, β- amino-α,β-enones are attractive intermediates that syndicate the ambident behaviours of nucleophilicity and electrophilicity of enones at the same time. β-amino-α,β-enones have been known as acceptors in both 1,2- and 1,4- additions that make them good intermediate compounds for annulation to different heterocycles.

Funder

Deanship of Scientific Research at Umm Al-Qura University, Saudi Arabia

Publisher

Bentham Science Publishers Ltd.

Subject

Organic Chemistry,Biochemistry

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