Affiliation:
1. Department of Chemistry, GLA University, Mathura, Uttar Pradesh, India
Abstract
Aim:
To synthesize and characterize organomercury complexes.
Background:
Organomercury complexes have reported for different antimicrobial activities.
Objectives:
Synthesis of organomercury complexes with piperidine thiohydrazide ligand and characterization,
applications.
Methods:
Complexes were synthesized by modified reported methods. Spectral (IR, UV, 1HNMR) and
TG/DTA analyses were used to characterize the generated complexes. For some of the complexes produced,
chemical kinetic characteristics such as activation energy, order of reaction, heat of reaction,
and apparent activation entropy were determined. The antimicrobial activities were also reported.
Results:
In these synthesized complexes, the thiohydrazides act as bidentate ligands, coordinating
through the thiol Sulphur and terminal nitrogen. Elemental and spectral data of the ligand and complexes
show that the compounds are pure enough.
Conclusion:
Every synthesized complex is diamagnetic in nature. The complexes have better antibacterial
activities against Z. mobilis than E. coli, with A. niger > Cerveleria in case of antifungal activities.
Publisher
Bentham Science Publishers Ltd.
Subject
Organic Chemistry,Biochemistry
Cited by
2 articles.
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