Diarylmethanols Synthesis by Nickel(II)-catalyzed Addition of Arylboronic Acids to Aryl Aldehydes-Reference-Cited by-同舟云学术

Diarylmethanols Synthesis by Nickel(II)-catalyzed Addition of Arylboronic Acids to Aryl Aldehydes

Published:2020-03-25 Issue:4 Volume:17 Page:248-253
ISSN:1570-1786
Container-title:Letters in Organic Chemistry
language:en
Short-container-title:LOC

Author:

Bie Fusheng¹^ORCID,Liu Xuejing¹,Wang Meng²,Cui Haizhu³,Li Tang³,Ma Jie³,Cao Han¹

Affiliation:

1. Engineering and Technology Institute of LuNan Coal Chemical Engineering, ZaoZhuang University, No. 1 Bei’an Road, Zaozhuang 277160, China

2. Longkou Entry-Exit Inspection and Quarantine Bureau, Longkou 265700, China

3. College of Chemistry, Chemical Engineering and Materials Science, ZaoZhuang University, No. 1 Bei’an Road, Zaozhuang 277160, China

Abstract

A practical procedure for the addition of arylboronic acids to aromatic aldehydes has been developed in the presence of NiCl2(PPh3)2/1,3-bis-(2,6-diisopropylphenyl)imidazolium chloride (IPr·HCl) system with good yield. Generally, electron-rich and -neutral aryl aldehydes showed excellent reactivity and provided desired products in high yields. This procedure will provide new way to the synthesis of diarylmethanols.

Funder

National Natural Science Foundation of China

Publisher

Bentham Science Publishers Ltd.

Subject

Organic Chemistry,Biochemistry

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