Affiliation:
1. Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, Kyiv-94, 02660, Ukraine
Abstract
Abstract:
This account reviews synthetic strategies for constructing and transforming
CF3S(O) structural moiety developed during the last decades. Existing paths to the synthesis
of CF3S(O)-containing organic molecules are demonstrated. Among these are direct trifluoromethanesulfinylation
reactions, oxidation of compounds having CF3S function, substitutive
trifluoromethylation reactions of sulfinic acid halides and esters, and rearrangement reactions.
The reactivity and substituent modification procedures are covered. Also included are sections
on the synthetic application of the CF3S(O)-bearing molecules for the design of biologically
important molecules and synthesis of other organofluorine compounds.
Funder
National Academy of Science of Ukraine
Publisher
Bentham Science Publishers Ltd.
Reference185 articles.
1. Cahard D.; Ma J-A.; Eds.; Emerging Fluorinated Motifs: Synthesis,
Properties, and Applications; Wiley-VCH: Weinheim, 2020
2. Ni C.; Hu M.; Hu J.; Good partnership between sulfur and fluorine: Sulfur-based fluorination and fluoroalkylation reagents for organic synthesis. Chem Rev 2015,115(2),765-825
3. Kukhar V.; Romanenko V.; Phosphorus and fluorine-the union for bioregulators. Kem Ind 2007,56(6),329-344
4. Beier P.; Zibinsky M.; Prakash G.K.S.; In: Organic Reactions 2016,Vol. 91,1-492
5. Liu X.; Xu C.; Wang M.; Liu Q.; Trifluoromethyltrimethylsilane: Nucleophilic trifluoromethylation and beyond. Chem Rev 2015,115(2),683-730
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