Affiliation:
1. Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan
Abstract
Halogen bond interactions, which take place between an electrophilic halogen
and the electron-pair of a Lewis base and exhibit high directionality (approximately 180°),
are non-covalent bond interactions similar to the hydrogen bond interaction. Many reports
on halogen bond interactions have been published thus far, but many of them discuss halogen
bond in the context of crystal engineering of supramolecular architecture. Since a
seminal report by Bolm in 2008, halogen bond-assisted or -promoted organic synthesis has
received significant attention. This review aims to introduce the molecular design of suitable
halogen bond donors and organic transformations involving halogen bond interactions
to afford a variety of organic compounds.
Publisher
Bentham Science Publishers Ltd.
Cited by
13 articles.
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