Affiliation:
1. Universidad Autónoma de Zacatecas
2. CINVESTAV-Saltillo
Abstract
The objective of this work is to study the process of phosphatizing with manganese by immersion. In the literature there is not enough information on the phosphate process with manganese phosphate, hence the main contribution of the present. The methodology involves an electrochemical study, using open circuit potential techniques in order to follow the kinetics of the process. In the same way, the characterization of the coating formed on the surface of each steel used was carried out using scanning electron microscopy and X-ray energy dispersion spectroscopy. Through this technique, the time was found in which the internal layer of the coating developed on the phosphatized substrates, both on the rough and the rough sides of the steel samples. The results obtained show that the formation of the manganese phosphate coating on the steels depends both on the grain size of the steels at the beginning of the process, as well as on the surface finish to which the steel surface is subjected, resulting in an increase in the size of the crystals, and affecting the rate of disintegration and growth of the same.
Reference18 articles.
1. [1] Callister Jr. W. D. (1995), “Introducción a la ciencia de los materiales”, 3ra edición, editorial Reverte S.A., Barcelona, España.
2. [2] T.S.N. Sankara Narayanan, T. (2005). Surface pretreatment by phosphate conversion coatings – a review. Adv.Mater.Sci. 9, 130-177.
3. [3] Gruss B. (2010) “Iron phosphating”. Journal Metal finishing, volume 108, issue 1, pages 33-37.
4. [4] Delgado Aguilar A. (2016). “Estudio Fenomenológico de las etapas críticas del proceso de fosfatizado con Zn-Mn de láminas de acero formables”, Centro de investigaciones y de Estudios Avanzados del Instituto Politécnico Nacional Unidad Saltillo.
5. [5] López León Servando (2008). Distribución del activador de Ti y su efecto en la formación de los recubrimientos de fosfato. Tesis de Maestría. Centro de Investigación y Desarrollo Tecnológico en Electroquímica. Querétaro.