Optimal Curing of Rubber Compounds with Reversion Type Cure Behavior

Author:

Han In-Su1,Chung Chang-Bock1,Lee Jae-Woo1

Affiliation:

1. 1Faculty of Applied Chemistry, College of Engineering, Chonnam National University, Kwangju 500-757, Korea; e-mail: chungcb@chonnam.chonnam.ac.kr

Abstract

Abstract A systematic procedure is presented for the optimal curing of rubber compounds showing reversion type cure behavior. First, a cure kinetic model is proposed that can explain the reversion and the induction period commonly found in the vulcanization of rubber compounds. The state of cure behavior is analyzed as a function of cure temperature and time on the basis of the derived kinetic model. Then, the problem of determining optimal cure temperature profile for a rubber slab in a simple cure press is addressed and formulated into a constrained dynamic optimization problem. Finally, numerical algorithms and simulation results are presented to demonstrate the proposed cure optimization procedure.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

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