Affiliation:
1. 1Institute of Polymer Engineering, The University of Akron, Akron, OH 44325-0301
Abstract
Abstract
Apparatus has been constructed to abrade the flat surface of a rubber disk by rotating it against a stationary knife-blade scraper at constant frictional torque. The ratio of worn surface area to sample volume is relatively large, giving high sensitivity of measurement. Rates of abrasion were measured for several rubber compounds over a range of frictional torque from 0.05 to 1.2 Nm, corresponding to frictional work input from 150 to 3,600 J/m2 per rotation. For some materials, notably SBR compounds, the rate of abrasion decreased markedly as the experiment continued, due to rapid wear and blunting of the blade. Polybutadiene compounds caused much slower wear. Different blades were worn away at different rates, a zirconia blade showing the least wear. Also different elastomers showed different sensitivities to blade sharpness, the rate of abrasion of a high-styrene (48%) SBR compound being reduced the most with a blunted blade whereas the abrasion rate of polybutadiene (BR) was much less affected. Measurements were carried out with blades of known sharpness for several representative rubber compounds at various fnctional torques and at two temperatures, 25°C and 100°C. The high-styrene SBR compound showed the lowest rate of abrasion Unusually rapid abrasion was observed for SBR and BR compounds when the frictional work input exceeded a critical value, close to the tear ( fracture) energy at the same temperature. Also, periodic fluctuations in rate of abrasion were observed for rapidly-aging compounds at high temperatures. This is attributed to repeated formation and removal of a weakened surface layer.
Subject
Materials Chemistry,Polymers and Plastics
Cited by
25 articles.
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