Affiliation:
1. School of Energy Power and Mechanical Engineering North China Electric Power University Beijing China
2. School of Mechanical Engineering Dongguan University of Technology Dongguan China
Abstract
AbstractRecently, high‐entropy perovskite oxides (HEPOs) have received increasing interest for energy storage applications owing to their unique structure, huge composition space, and promising properties. However, designing HEPOs with improved energy storage performance remains a challenge. In this study, various HEPOs were designed by partially replacing Zr4+ for Ti4+ in (Bi0.4Ba0.2K0.2Na0.2)TiO3 medium‐entropy ferroelectric ceramics. The resulting ceramics exhibited a pseudo‐cubic structure. With increasing Zr4+ content, the ceramics gradually transformed into relaxor ferroelectrics. The energy storage performance of the ceramics depended on the Zr4+ content. The sample with 20 mol% Zr4+ showed the best energy storage performance with a maximum reversible energy density of 2.47 J/cm3 and an energy storage efficiency of 82.3% at a low applied electric field (224 kV/cm). This study obtained a promising material for the new generation dielectric energy storage capacitors and provided a novel method for enhancing energy storage performance.
Subject
Materials Chemistry,Ceramics and Composites
Cited by
4 articles.
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