Experimental values and ERAS model calculations for excess molar volumes and enthalpies of the ternary system 2-butanol + 1,3-dioxolane + cyclohexane-Reference-Cited by-同舟云学术

Experimental values and ERAS model calculations for excess molar volumes and enthalpies of the ternary system 2-butanol + 1,3-dioxolane + cyclohexane

Published:2003-05-01 Issue:5 Volume:81 Page:357-363
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Gascón Ignacio,Martín Santiago,Giner Beatriz,Haro Marta,Lafuente Carlos

Abstract

Densities and heats of mixing for the ternary system 2-butanol + 1,3-dioxolane + cyclohexane have been measured at 298.15 and 313.15 K. Excess molar volumes and excess molar enthalpies have been calculated from experimental data and fitted by the RedlichKister equation. The ERAS model has been used to calculate excess molar properties of the ternary mixture from parameters obtained from the constituent binary mixtures.Key words: excess properties, ERAS model.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v03-068

Reference26 articles.

1. Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 1. Binary Systems 1,4-Dioxane + n-Alkanes

2. Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 2. Binary Systems 1,3-Dioxolane + n-Alkanes

3. Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 3. Binary Systems {Tetrahydrofuran, Tetrahydropyran, 1,4-Dioxane, or 1,3-Dioxolane + Cyclohexane or Toluene}

4. Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 4. Binary Systems 1,4-Dioxane + 1-Alkanols

5. Heat Capacities, Excess Enthalpies, and Volumes of Mixtures Containing Cyclic Ethers. 5. Binary Systems {1,3-Dioxolane + 1-Alkanols}

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