RELAXATION OF SURFACE PRESSURE AND COLLAPSE OF UNIMOLECULAR FILMS OF STEARIC ACID

Author:

Rabinovitch W.,Robertson R. F.,Mason S. G.

Abstract

A study has been made of the time variations of π–A isotherms of stearic acid films at air/water interfaces using an automatic recording surface balance of the vertical pull type. The existence of coherent films below molecular areas of 22 sq. Å/molecule has been found to be dependent on the temperature, rate of compression, and the history of compression of a given film. The behavior at or near collapse, the decrease in π with time after sudden compression (relaxation), and the increase in π with time after sudden expansion (recovery) have been studied.The results have been interpreted on the basis of structural changes in the monolayer.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Reference11 articles.

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