Approximate method for calculating the third virial coefficient of a gaseous mixture

Author:

Orentlicher M.,Prausnitz J. M.

Abstract

An approximation is suggested for calculating the third virial cross-coefficient Cijk from available generalized tables for pure-component third virial coefficients Ciii which are based on any one of several, spherically symmetric potential functions. A comparison of calculated results with the very limited experimental data now available indicates that the suggested approximation can reproduce the experimental results essentially within the probable (large) experimental uncertainty.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 16 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Generalised virial equation of state for natural gas systems;Fluid Phase Equilibria;2005-04

2. Rayleigh-Bénard convection in binary-gas mixtures: Thermophysical properties and the onset of convection;Physical Review E;1997-06-01

3. Virial Description of Two-Component Adsorption on Homogeneous and Heterogeneous Surfaces;Industrial & Engineering Chemistry Research;1997-06-01

4. Equations of State for the Lennard–Jones Mixtures at High Temperatures;Bulletin of the Chemical Society of Japan;1991-11

5. Excess molar enthalpies of {xH2O +(1 –x)C5H12}(g) up to 698.2 K and 14.0 MPa;Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases;1988

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