Abstract
Kinetics of the reaction between N(III) and Cl(V) have been studied in water and water–dioxan solutions. The rate equation of the reaction in each solvent could be written as[Formula: see text]and the rate rises as the dielectric constant of the medium is lowered. This observation is in accord with suggested mechanistic details involving the intermediate H2NClO5.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
5 articles.
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1. Kinetics and Mechanism of the Chlorate–Nitrous Acid Reaction;Inorganic Chemistry;2017-09-05
2. The Chlorate-Iodine-Nitrous Acid Clock Reaction;PLoS ONE;2014-10-14
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