Prins cyclization of α-bromoethers under basic conditions-Reference-Cited by-同舟云学术

Prins cyclization of α-bromoethers under basic conditions

Published:2013-12 Issue:12 Volume:91 Page:1193-1201
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Arpin Patrice¹,Hill Bryan¹,Larouche-Gauthier Robin¹,Spino Claude¹

Affiliation:

1. Département de chimie, Université de Sherbrooke, 2500 boul. Université, Sherbrooke, QC J1K 2R1, Canada.

Abstract

α-Bromoethers have been found to undergo Prins-type cyclization under basic conditions and without the need to add a promoter. The products are those derived from a Markovnikov addition on the pendant alkene. However, the stereochemistry and even the structure of the products sometimes differ from those expected with the classical Lewis-acid-catalyzed Prins reaction of acetals.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2013-0337

Reference60 articles.

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