13C nuclear magnetic resonance spectra of some halosteroids, 6-ketosteroids, and related compounds-Reference-Cited by-同舟云学术

13C nuclear magnetic resonance spectra of some halosteroids, 6-ketosteroids, and related compounds

Published:1979-12-01 Issue:23 Volume:57 Page:3069-3072
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Holland Herbert L.,Thomas Everton M.

Abstract

The 13Cmr spectra of 21-haloprogesterones have been assigned, and chemical shifts compared with those of simple α-haloketones. In addition, the 13Cmr spectra of some C-5α and C-6β halosteroids are presented, and long range 13C—19F coupling observed between C-19 and the C-6β fluorine in some cases. The spectra of several oxygenated analogues and of a series of 5α-hydroxy-6-ketosteroids are also discussed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v79-501

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