Abstract
The structure of the 4d Rydberg term complex of the nitric oxide molecule has been studied by rotational analyses of the following bands photographed with spectrographs of high resolving power: (i) the weak band 4d–X2Π observed at 1470 Å in the absorption spectrum, (ii) the group 4d–3p of Rydberg–Rydberg bands observed as 4d–C2Π (6400 Å) and 4d–D2Σ+ (6800 Å) bands in the emission spectrum of a discharge. A type of l uncoupling of the Rydberg electron of the molecule is found very similar to the case already known for the 3d complex of NO. Constants characterizing the d complexes are calculated, and a comparison of the 3d and 4d complex is made.
Publisher
Canadian Science Publishing
Subject
General Physics and Astronomy
Cited by
31 articles.
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