PHOTOLYSIS OF MERCURY DIMETHYL

Author:

Rebbert Richard E.,Steacie E. W. R.

Abstract

The photolysis of mercury dimethyl was investigated over the temperature range from 125° to 250 °C. The results indicate that methane is formed only by an abstraction reaction and ethane is formed only by recombination, at least under the conditions used in these experiments. It is concluded that the activation energy of the reaction[Formula: see text]is 10.8 ± 0.3 kcal./mole.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Reference1 articles.

Cited by 22 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Reaktionsgeschwindigkeiten;Eigenschaften der Materie in Ihren Aggregatzuständen;2013

2. The photochemical decomposition of azoethane;Bulletin des Sociétés Chimiques Belges;2010-09-01

3. Photochemical conversion of trichloromethyl derivatives of mercury in the solid phase;Bulletin of the Academy of Sciences of the USSR Division of Chemical Science;1974-09

4. Chapter 4 The Decomposition of Metal Alkyls, Aryls, Carbonyls and Nitrosyls;Decomposition of Inorganic and Organometallic Compounds - Homogeneous Decompostion of Hydrides, Decompostion of Inorganic Oxides and Sulphides; Halides and Derivatives; Metal Alkyls, Aryls, Carbonyls and Nitrosyls;1972

5. Kinetic data for hydrogen and deuterium atom abstraction by methyl and trifluoromethyl radicals in the gaseous phase;Chemical Reviews;1971-06-01

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