Congo red filtration by polyacrylonitrile-based copolymer membranes

Abstract

In this study, Congo red removal from wastewater by a filtration method was studied via membranes obtained from polyacrylonitrile-co-poly(2-ethylhexylacrylate) copolymers having various monomer ratios and polyacrylonitrile-co-poly(2-ethylhexylacrylate)/polyaniline blends with various polyaniline contents. It was found that the dye rejection value increased with acrylonitrile content in polyacrylonitrile-co-poly(2-ethylhexylacrylate) membranes. Also, blending copolymers with polyaniline enhanced the dye rejection rate. The performance of membranes showed incremental increase with increase in the polyaniline content. Both pH and concentration effects on the dye rejection rate of membranes were evaluated. The performance of polyacrylonitrile-co-poly(2-ethylhexylacrylate) membranes did not change significantly, whereas polyaniline-containing membranes had higher dye rejection rates at acidic pH levels. PAN(92)-co-P2EHA(8)-PANI(15%) demonstrated the highest dye rejection value of 99.7% at pH 3 when the feed concentration was 50 ppm. It also showed good resistance to increase in feed concentration. It had dye rejection values of 97.2% and 88.5% for 100 and 200 ppm feed concentrations, respectively.