Vibrational Spectra of SiH4 and SiD4–SiH4 Mixtures in the Condensed States

Author:

Fournier R. P.,Savoie R.,The Nguyen Dinh,Belzile R.,Cabana A.

Abstract

The i.r. and Raman spectra of liquid and crystalline SiH4 and SiD4–SiH4 mixtures have been recorded. The spectra show striking changes when the crystal undergoes the solid–solid phase transition. Phase I is disordered. Possible site, and factor groups for the low temperature crystalline phase are proposed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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