Abstract
The hydrolyses of a series of organic halides, nitrates, sulphonates, and perchlorates are examined from the standpoint of thermodynamics, kinetics, temperature dependence, isotope effects, the Kurz equation, and the Guthrie linear free energy relationship. The thermodynamics of several definite bimolecular displacements are also examined. Some mechanistic revisions are suggested to reach an improved accommodation with the experimental observations.Key words: kinetics, thermodynamics, hydrolytic displacements, mechanism, ionic displacements, nucleofugality, linear free energy relationships.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
5 articles.
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