Abstract
Magnetic susceptibility measurements have shown that the chromium atoms in the toluene–chromyl chloride complex are tetravalent. The structure of the complex and the reaction mechanism are discussed. Spectroscopic evidence has been found of the initial formation of a π-complex. The products of reaction of chromyl chloride and ethylbenzene, isopropylbenzene, tetralin, and indane have been determined.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
16 articles.
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1. The Étard Reaction: A DFT Study;Inorganic Chemistry;2011-05-27
2. Étard Reaction;Comprehensive Organic Name Reactions and Reagents;2010-09-15
3. Oxidation of aromatic amines with chromyl chloride-II;Tetrahedron;1986-01
4. Oxidation of aromatic amines with chromyl chloride-I;Tetrahedron;1986-01
5. Oxidation by Oxochromium(VI) Compounds;Organic Syntheses by Oxidation with Metal Compounds;1986