Solid-state 207Pb nuclear magnetic resonance studies of adducts of 1,10-phenanthroline with lead(II) halides-Reference-Cited by-同舟云学术

Solid-state 207Pb nuclear magnetic resonance studies of adducts of 1,10-phenanthroline with lead(II) halides

Published:2011-07 Issue:7 Volume:89 Page:863-869
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Glatfelter Alicia¹,Bai Shi¹,Dmitrenko Olga¹,Perry Dale L.²,Van Bramer Scott E.³,Dybowski Cecil¹

Affiliation:

1. Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA.

2. Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.

3. Department of Chemistry, Widener University, Chester, PA 19013, USA.

Abstract

Experimental and predicted 207Pb nuclear magnetic resonance (NMR) parameters of solid-state coordination complexes of lead(II) bromide, lead(II) iodide, and lead(II) chloride with 1,10-phenanthroline are reported. Structural and electronic differences between the 1:1 and 1:2 adducts are reflected by the NMR parameters. The NMR chemical shieldings of the isostructural complexes indicate that the electronic state of the lead(II) center depends on the number of ligands and the halogen anion. The NMR results suggest that the 1:2 adduct may be more stereochemically active than the 1:1 adduct.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v10-176

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