Author:
Thiele Everett,Wilson David J.
Abstract
Slater's theory of unimolecular reactions is tested by comparing theoretical and experimental values of the pressure at which the rate constant has fallen off from the high-pressure limit by 5%. A simplified method is used for calculating lower bounds to the theoretical value of this pressure. Agreement with experimental data on cyclobutane, cyclobutene, and nitrogen pentoxide is rather poor; experimental values are lower than the calculated lower bounds.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
15 articles.
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