The reaction of active nitrogen with fluoroethylenes

Author:

Jones William E.,Ahmed Mahmooda G.

Abstract

The reactions of active nitrogen with the fluoroethylenes C2H3F, 1,1-C2H2F2, C2HF3, and C2F4 have been investigated in a conventional flow system using a mass spectrometer to detect products and intermediate species. Addition of various gases (H, H2, NH3, CH4, N2O, [Formula: see text], and F) to the reacting mixtures provides evidence that both Hand F atoms play significant roles in the reaction mechanisms, while [Formula: see text] does not. A brief discussion of possible mechanisms is presented.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. The Unreactive Nature of N(24S) to Unsaturated Hydrocarbons;Bulletin of the Chemical Society of Japan;1986-05

2. Elements of group 5;Coordination Chemistry Reviews;1984-06

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