Abstract
Cycloalkanone oximes were shown to give the corresponding alkanoic acid amides when irradiated in iso-propanol. α-Alkylated cyclohexanone oximes gave products corresponding to preferential cleavage on the side of the more substituted carbon atom. iso-Propanol was shown to transfer two hydrogen atoms specifically to the excited oxime molecule, acetone being formed in the process. In 1% aqueous solution, irradiation of oximes gave the corresponding ketones, ammonia, and oxygen.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
33 articles.
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