REACTIONS OF (i) ALUMINUM TERTIARY BUTOXIDE WITH ACETYL CHLORIDE AND (ii) ALUMINUM CHLORIDE WITH TERTIARY BUTYL ACETATE

Author:

Mehrotra R. C.,Misra R. A.

Abstract

The reactions between aluminum tertiary butoxide and acetyl chloride have been studied. The addition of 1 mole of acetyl chloride to aluminum tertiary butoxide forms monochloride ditertiary butoxide, which, with another mole of acetyl chloride, appears to give the dichloride monotertiary butoxide derivatives. Further, these products appear to react with tertiary butyl acetate formed in the reaction itself, giving acetate derivatives. The above is confirmed by a detailed study of the reactions between aluminum chloride and tertiary butyl acetate, which have been found to result in the acetate derivatives. A plausible mechanism has been suggested.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Reference11 articles.

Cited by 8 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Homometallic Alkoxides;Alkoxo and Aryloxo Derivatives of Metals;2001

2. Aluminium alkoxides, β-diketonates and carboxylates;Polyhedron;1991-01

3. Halide alkoxides of beryllium;Journal of the Less Common Metals;1969-02

4. Alkoxides and alkylalkoxides of metals and metalloids;Inorganica Chimica Acta Reviews;1967-12

5. Bromide Alkoxides of Tantalum;Journal f�r Praktische Chemie;1967-08

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