Preparation of shrinkage-free alkali-activated slag material using MgO as both the activator and the expansive agent

Abstract

Alkali-activated slag (AAS) materials activated by NaOH or waterglass has been long-term criticized for the developed substantial shrinkage. To this regard, this paper explored MgO as both an activator and an expansive agent to prepare shrinkage-free AAS. The setting time, mechanical strength, pore structure, autogenous shrinkage, drying shrinkage, and hydration products of MgO-activated AAS were studied. Experimental results confirmed that MgO can effectively mitigate the autogenous shrinkage and drying shrinkage of AAS via the expansive deformation caused by Mg(OH)2. Generally, AAS with a higher dosage of MgO developed less shrinkages and refiner pore structures with more gel pores. An optimal dosage of 9% MgO is recommended to prepare AAS with near zero shrinkage and the highest flexural strength.