Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with tertiary phosphine and phosphite ligands. The isolation and characterization of the 1:1 adducts Re2X4(dppm)2(PR3) and Re2Cl4(dppm)2[P(OR)3] and the crystal structure of [Re2Cl3(dppm)2(NCEt)2]PF6-Reference-Cited by-同舟云学术

Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with tertiary phosphine and phosphite ligands. The isolation and characterization of the 1:1 adducts Re2X4(dppm)2(PR3) and Re2Cl4(dppm)2[P(OR)3] and the crystal structure of [Re2Cl3(dppm)2(NCEt)2]PF6

Published:1990-06 Issue:1 Volume:172 Page:65-71
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Fanwick Phillip E.,Ju-Sheng Qi,Keng-Yu Shih,Walton Richard A.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference21 articles.

1. Complex halides of the transition metals. XX. Reactions of the octahalodirhenate(III) anions with bidentate tertiary phosphines and arsines and some related reactions of dimers of the type Re2X4(PR3)4

2. Structural characterization of the triply bonded dirhenium(II) complexes Re2Cl4(.mu.-Ph2PCH2PPh2)2 and .alpha.-Re2Cl4(Me2P(CH2)2PMe2)

3. Isomerization in metal-metal bonded M2L10 systems involving cis and trans sets of bis(diphenylphosphino)methane ligands

4. Some recent developments in the chemistry of multiply bonded dimetal complexes that contain the intramolecular bridging phosphine ligands R2P(CH2)nPR2

5. The triply-bonded complex tetrachlorobis[bis(diphenylphosphino)methane] dirhenium(II) and related species, and their use as reagents in dirhenium chemistry

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