The role of pe, pH, and carbonate on the solubility of UO2 and uraninite under nominally reducing conditions

Author:

Casas Ignasi,de Pablo Joan,Giménez Javier,Torrero M.Elena,Bruno Jordi,Cera Esther,Finch Robert J.,Ewing Rodney C.

Publisher

Elsevier BV

Subject

Geochemistry and Petrology

Reference35 articles.

1. Aguilar M., Casas I., de Pablo J., Giménez J., and Torrero M. E. (1991) Preliminary solubility studies of uranium dioxide under the conditions expected in a saline repository. ENRESA Tech. Rept. 03/91.

2. The determination of the solubility of amorphous UO2 (s) and the mononuclear hydrolysis constants of uranium (IV) at 25°C;Bruno;Mat. Res. Soc. Symp. Proc.,1987

3. A reinterpretation of the solubility product of solid uranium (IV) dioxide;Bruno;Acta Chem. Scand.,1989

4. Validation of the SKBU1 uranium thermodynamic database for its use in geochemical calculations with EQ3/6;Bruno;Mat. Res. Soc. Symp. Proc.,1989

5. The kinetics of dissolution of UO2 under reducing conditions and the influence of an oxidized surface layer (UO2+x);Bruno;Geochim. Cosmochim. Acta,1991

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