Unexpected formation of an oxetane cycle by oxidation of diacetonide of 20-hydroxyecdysone with oxygen in an alkaline medium

Author:

Odinokov Victor N.,Galyautdinov Ilgiz V.,Ibragimova Aliya Sh.,Veskina Natalya A.,Khalilov Leonard M.,Dolgushin Fedor M.,Starikova Zoya A.

Publisher

Elsevier BV

Subject

General Chemistry

Reference12 articles.

1. D.Caine, Organic Reactions. Reduction and Related Reactions of α,β-Unsaturated Carbonyl Compounds with Metals in Liquid Ammonia, ed. W. G. Dauben, Wiley, New York, 1976, vol. 23, p. 1.

2. H. L. Dryden, Jr., Organic Reactions in Steroid Chemistry. Reduction of Steroids by Metal-Ammonia Solutions, eds. J. Fried and J. A. Edwards, Van Nostrand Reinhold, New York, 1972, vol. 1, p. 27.

3. Fe(II)-Induced Fragmentation Reaction of ?-Hydroperoxy-?,?-enones. Part 1. Synthesis of 13(14?8)-abeo-Steroids

4. APEX II Software Package, Bruker AXS Inc., Madison, WI 5317, 2005.

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