The reactions of tricobalt alkylidyne complexes [Co3(μ3−CR)(CO)9](R = Me, CO2Me) with the vinyl phosphine ligands PPh2CHCH2 and cis-Ph2PCHCHPPh2; crystal structure of [Co3(μ3−CCO2Me)(μ-Ph2PCHCHPPh2)(CO)7]-Reference-Cited by-同舟云学术

The reactions of tricobalt alkylidyne complexes [Co3(μ3−CR)(CO)9](R = Me, CO2Me) with the vinyl phosphine ligands PPh2CHCH2 and cis-Ph2PCHCHPPh2; crystal structure of [Co3(μ3−CCO2Me)(μ-Ph2PCHCHPPh2)(CO)7]

Published:1996-02 Issue:1-2 Volume:508 Page:137-145
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Acum Gillian A.,Mays Martin J.,Raithby Paul R.,Solan Gregory A.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference35 articles.

1. η-Cyclopentadienyltungsten compounds with vinyl- and allyl-phosphine ligands

2. The reaction of [Mn2{µ-σ:η2-C(R)CHR}(µ-PPh2)(CO)7](R = H or Ph) with nucleophiles: X-ray crystal structures of [N(PPh3)2][Mn2(µ-H){µ-C(O)C(Ph)CHPh}(µ-PPh2)(CO)6], [Mn2{PPh2C(Ph)CHPh}(CO)9], [Mn2(µ-PPh2CHCH2)(CO)8], [Mn2{µ-C(O)C(Ph)CHPh}(µ-PPh2)(CO)6(CNBut)2], [Mn2{µ-σ:η2-C(Ph)CHPh}(µ-PPh2)(CO)6(CNBut)], and [Mn(µ-PPh2CHCH2)(CO)7(PEt3)]

3. Transformations of a µ2-vinyl ligand at a dimanganese centre and the flexibility of µ2-acyl lignads; X-ray crystal structures of [(Ph2P)2N][Mn2(µ2-H){µ2-C(O)CPh : CHPh}(µ2-PPh2)(CO)6], [Mn2{µ2-C(O)CPh : CHPh}(µ2-PPh2)(CO)6(CNBut)2], and [Mn2{σ : η3-P(Ph)2CH : CH2}(CO)7(PEt3)]

4. Facile synthesis and structural characterization of [(Ph2PCHCH2)(.mu.-.eta.3-Ph2PCHCH2)PdI]2(BF4)2: unprecedented formation of a structurally unusual Palladium(I) complex

5. Cluster Chemistry

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