Extension of the e.t. mechanism of aromatic nitration to the formation of Grignard reagents of RX (R = alkyl, aryl, cyclopropyl, vinyl). The ion pair collapse versus radical pair collapse hypothesis-Reference-Cited by-同舟云学术

Extension of the e.t. mechanism of aromatic nitration to the formation of Grignard reagents of RX (R = alkyl, aryl, cyclopropyl, vinyl). The ion pair collapse versus radical pair collapse hypothesis

Published:2001-07 Issue:7 Volume:4 Page:567-570
ISSN:1387-1609
Container-title:Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry
language:en
Short-container-title:Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry

Author:

Berg Ulf,Bodineau Nicolas,Négrel Jean-Claude,Mattalia Jean-Marc,Vitaliy Timokhin ,Handoo Kishan,Marchi Caroline,Chanon Michel

Publisher

Elsevier BV

Subject

General Chemistry

Reference26 articles.

1. THE REDUCING ACTION OF A MIXTURE OF MAGNESIUM IODIDE (OR BROMIDE) AND MAGNESIUM ON AROMATIC KETONES. PROBABLE FORMATION OF MAGNESIUM SUBIODIDE (OR SUBBROMIDE)

2. Grignard Reagents: New Developments;Garst,2000

3. Electron transfer at the solid liquid interface; new insights on the mechanism of formation of the grignard reagent

4. Grignard reagent formation from aryl halides. There is no aryl radical intermediate along the dominant reaction channel

5. Formation of Grignard Reagents from Aryl Halides: Effective Radical Probes Hint at a Nonparticipation of Dianions in the Mechanism

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3. Radical clocks and electron transfer. Comparison of crown ether effects on the reactivity of potassium and magnesium towards 1-bromo-2-(3-butenyl)benzene. The incidence of homogeneous versus heterogeneous electron transfer on selectivity;Journal of Physical Organic Chemistry;2005

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