Stabilization of a Y-shaped CuI coordination in [CuPt2(PPh3)5(μ3-S)2]PF6 by Pt2(PPh3)4(μ-S)2 and its expansion to a pentanuclear aggregate [Cu{Pt2(PPh3)4(μ3-S)2}2]PF6. X-ray crystal structure of [CuPt2(PPh3)5(μ3-S)2]PF6-Reference-Cited by-同舟云学术

Stabilization of a Y-shaped CuI coordination in [CuPt2(PPh3)5(μ3-S)2]PF6 by Pt2(PPh3)4(μ-S)2 and its expansion to a pentanuclear aggregate [Cu{Pt2(PPh3)4(μ3-S)2}2]PF6. X-ray crystal structure of [CuPt2(PPh3)5(μ3-S)2]PF6

Published:1997-01 Issue:3 Volume:16 Page:377-382
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Huang Liu ,Tan Agnes L.,Yan Xu ,Mok K.F.,Hor T.S.Andy

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference28 articles.

1. Chemistry of platinum sulphido-complexes. Part 5. Synthesis and crystal and molecular structure of 3-(η-cyclo-octa-1,5-diene)bis(µ3-sulphido)-1,1,2,2-tetrakis(triphenylphosphine)diplatinum(II)rhodium(I) hexafluorophosphate–dichloromethane (1/1), [Pt2Rh(µ3-S)2(PPh3)4(η-C8H12)]PF6·CH2Cl2

2. Chemistry of platinum sulphido-complexes. Part 6. Reactions of [Pt2(µ-S)2(PPh3)4] with the rhodium complexes [(RhL2Cl)2](L = CO or C2H4) and [Rh(2,6-Me2C6H3NC)4]PF6. Crystal and molecular structures of [Pt2Rh(µ-S)2(PPh3)4(CO)2][Rh(CO)2Cl2]·C3H6O and [Pt2Rh(µ-S)2(PPh3)4(2,6-Me2C6H3NC)2]PF6

3. X-Ray photoelectron spectroscopic characterization of [{Pt(PPh3)2(µ3-S)}2PtCl2], [{Pt2(PPh3)4(µ3-S)2Cu}2(µ-dppf)][PF6]2[dppf = Fe (C5H4PPh2)2] and other heterometallic aggregates derived from [{Pt(PPh3)2(µ-S)}2]

4. Di-.mu.-sulfidotetrakis(triphenylphosphine)diplatinum as a metalloligand towards main-group Lewis acids. Crystal structures of two complex adducts of lead nitrate, [(PPh3)4Pt2(.mu.3-S)2Pb(NO3)2] and [(PPh3)4Pt2(.mu.3-S)2Pb(NO3)]PF6

5. Di-.mu.-sulfidotetrakis(triphenylphosphine) as a metalloligand toward main-group Lewis acids. A "Mexican-hat-like" structure for [Pt2Tl(.mu.3-S)2(PPh3)4]X (X = NO3, PF6) with a two-coordinate angular thallium(I)

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