Strictly regio- and stereo-controlled α-alkenylation of bicyclic enone derivatives via palladium-catalyzed cross coupling and its application to a formal synthesis of (±)-carbacyclin-Reference-Cited by-同舟云学术

Strictly regio- and stereo-controlled α-alkenylation of bicyclic enone derivatives via palladium-catalyzed cross coupling and its application to a formal synthesis of (±)-carbacyclin

Published:1998-06 Issue:25 Volume:54 Page:7057-7074
ISSN:0040-4020
Container-title:Tetrahedron
language:en
Short-container-title:Tetrahedron

Author:

Negishi Ei-ichi,Pour Milan,Cederbaum Frederik E.,Kotora Martin

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference48 articles.

1. Metal promoted cyclization. 7. Zirconium-promoted bicyclization of enynes

2. Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes

3. A selective method for the synthesis of stereodefined exocyclic alkenes via allylmetalation of propargyl alcohols

4. Metal-promoted cyclization. 19. Novel bicyclization of enynes and diynes promoted by zirconocene derivatives and conversion of zirconabicycles into bicyclic enones via carbonylation

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