Hydroxy group-assisted isomerization and alkylation of allylsilanes in basic media. α-(1-trimethylsilyallyl) ketone as an α-alkenyl ketone equivalent.
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference18 articles.
1. Reactions of allylsilanes and application to organic synthesis
2. Chemistry of organosilicon compounds 113 chemoselective allylation of carbonyl compounds with allylsilanes promoted by tetra--butylammonium fluoride. A new synthesis of homoallyl alcohols
3. Allyloxy carbanions. New synthesis of aldehydes via a .beta.-acyl carbanion equivalent
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