Anti-Markovnikov stereoselective addition of bis(trimethylsilyl)octadiene to ketal obtained by unprecedented retro-Claisen condensation of 3-hydroxy-2,4-pentanedione bis-ketal
Author:
Funder
CNRS
MEN
Publisher
Elsevier BV
Subject
General Chemical Engineering,General Chemistry
Reference56 articles.
1. Synthesis of 1,3-divinyl-2-methyl-2-alkylcyclopentanes by dialkylation of ethyleneketals with 1,8-bis(trimethylsilyl)-2,6-octadiene.
2. Dialkylation of β and γ-diketone monoethyleneketals by 1,8-bis(trimethylsilyl)-2,6-octadiene.
3. Stereoselective allylsilane additions to α-diketone diketals
4. Dialkylation of α-diketone ketals with 1,8-bis(trimethylsilyl)octa-2,6-diene
5. Diastereoselective diallylation of various butane-2,3-diacetals by allylsilane
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