Synthesis and reactivity studies of the diphosphine ligand 2-(ferrocenylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (fbpcd): Bridge-to-chelate ligand isomerization kinetics in Os3(CO)10(fbpcd) and X-ray diffraction structure of the ortho-metalated cluster HOs3(CO)9[μ-PhP(C6H4)CC(PPh2)C(O)CCH(C5H4FeCp)C(O)]-Reference-Cited by-同舟云学术

Synthesis and reactivity studies of the diphosphine ligand 2-(ferrocenylidene)-4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (fbpcd): Bridge-to-chelate ligand isomerization kinetics in Os3(CO)10(fbpcd) and X-ray diffraction structure of the ortho-metalated cluster HOs3(CO)9[μ-PhP(C6H4)CC(PPh2)C(O)CCH(C5H4FeCp)C(O)]

Published:2007-08 Issue:14 Volume:26 Page:3585-3594
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Watson William H.,Poola Bhaskar,Richmond Michael G.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference40 articles.

1. Phosphorus-carbon bond cleavage and tetrahedrane cluster activation in the reaction between bis(diphenylphosphino)maleic anhydride (BMA) and PhCCo3(CO)9. Syntheses, kinetic studies, and x-ray diffraction structures of PhCCo3(CO)7(bma) and [cyclic] Co3(CO)6(.mu.2-.eta.2,.eta.1-C(Ph)C:C(PPh2)C(O)OC(O))(.mu.2-PPh2)

2. Phosphine Ligand Attack at Both the Methylidyne Cap and the CpNi Center in HCCo2NiCp(CO)6 by 2,3-Bis(diphenylphosphino)maleic Anhydride (bma): P−C Bond Cleavage Reactivity, Kinetics, and X-ray Structures of the Zwitterionic Clusters Co2NiCp(CO)4(μ-CO)[μ2,η2,η1-C(H)PPh2CC(PPh2)C(O)OC(O)] and Co2NiCp(CO)4[μ2,η2,σ-C(H)PPh2CCC(O)OC(O)](μ2-PPh2)

3. Ligand substitution in the mixed-metal cluster PhCCo2Ni(CO)6Cp by 2,3-bis(diphenylphosphino)maleic anhydride (bma): An intimate picture involving the stepwise conversion of the trinuclear cluster PhCCo2Ni(CO)4(η2-bma)Cp to the mononuclear compound CpNi[PPh2CPhCC(PPh2)C(O)OC(O)]

4. Synthesis and diphosphine ligand fluxionality in Os3(CO)10(bmi): Kinetic evidence for nondissociative diphosphine isomerization and X-ray crystal structure of 1,1-Os3(CO)10(bmi)

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